The hydrated (with water) red form can be made by reacting cobalt(II) oxide or cobalt(II) hydroxide with hydrochloric acid. Hydrochloric acid works the best, but sodium chloride can be used too. The German chemist Alfred Werner was awarded the Nobel prize in 1913 for his studies on a series of these cobalt(III) compounds, work that led to an understanding of the structures of such coordination compounds. Lithium chloride 20 mM – Cobalt(II) chloride 5 mM – Sodium cacodylate Buffer pH 6.0; 50 mM – Dioxan 20% solution. 1 Product Result for an example. Zug KA, Warshaw EM, Fowler JF Jr, Maibach HI, Belsito DL, Pratt MD, Sasseville D, Storrs FJ, Taylor JS, Mathias CG, Deleo VA, Rietschel RL, Marks J. Patch-test results of the North American Contact Dermatitis Group 2005–2006. It can be used to make other cobalt compounds. It contains cobalt and chloride ions. Properties. It contains cobalt and chloride ions. Cobalt compounds are toxic in large quantities, like any other transition metal compounds. Structure of hexahydrate. Cobalt(II) chloride, also known as cobaltous chloride and cobalt dichloride, is a chemical compound. Cobalt(II) chloride is normally found in the red (or pink) form. The red form has water in it. It is a sky blue crystalline solid. Examples include: Otherwise, aqueous solutions of cobalt(II) chlorides behave like other cobalt(II) salts, such as precipitating CoS upon treatment with H2S. Wojakowska, A., Krzyżak, E. and Plińska, S. (2007): "Melting and high-temperature solid state transitions in cobalt(II) halides". 11.1.5 The unusual type of myocardiopathy recognized in 1965 and 1966 in Quebec (Canada), Minneapolis (Minnesota), Leuven (Belgium), and Omaha (Nebraska) was associated with episodes of acute heart failure (e/g/, 50 deaths among 112 beer drinkers). It contains cobalt in its +2 oxidation state. Other names Cobaltous chloride Cobalt dichloride [15], Cobalt is essential for most higher forms of life, but more than a few milligrams each day is harmful. For example, the reaction of 1-norbonyllithium with CoCl2 produces the brown, thermally stable cobalt(IV) tetralkyl[3][4] — the only compound of its kind for which the detailed structure is fully known[5]: Reaction of anhydrous CoCl2 with sodium cyclopentadienylide in THF gives the black sandwich compound cobaltocene. [6] An authoritative monograph[5] states, "Apart from CoF3, the only known halides of cobalt are the dihalides." Cobalt(II) chloride. This analysis changes considerably in the presence of ligands of greater Lewis basicity than chloride, such as amines. From Simple English Wikipedia, the free encyclopedia, Except where otherwise noted, data are given for materials in their,, Chemical articles with unknown parameter in Chembox, Articles containing unverified chemical infoboxes, Creative Commons Attribution/Share-Alike License. The blue form will absorb water from the air and turn red again. The anhydrous (without water) blue form can be made by reacting cobalt with chlorine. Cobalt(II) chloride, also known as cobaltous chloride and cobalt dichloride, is a chemical compound. To find more Cobalt(II) chloride information like chemical properties, structure, melting point, boiling point, density, molecular formula, molecular weight, physical properties and toxicity information. Its chemical formula is CoCl2. M. T. Saugier, M. Noailly, R. Cohen-Adad, F. Paulik, and J. Paulik (1977): "Equilibres solide ⇄ liquide ⇆ vapeur du systeme binaire. A different blue form is made when cobalt(II) chloride is reacted with a chemical compound that has chloride in it. Categories: Cobalt compounds | Inorganic compounds | Chlorides | Metal halides | IARC Group 2B carcinogens | Deliquescent substances. If it is made, it just drops a Cl from CoCl3, making CoCl2 (cobalt(II) chloride) again. The reduction potential for Co3+ + e- → Co2+ is more favorable (+1.92 V) than the reduction Cl2 to Cl- (+1.36 V). Unlike Co(II) complexes, Co(III) complexes are very slow to exchange ligands, so they are said to be kinetically inert. © 1997-2020 LUMITOS AG, All rights reserved,, Your browser is not current. "Cobalt chloride administration in athletes: a new perspective in blood doping? Find out more about the company LUMITOS and our team. When hydrochloric acid is added, the added chloride ions shift the equilibrium position in favour of blue [CoCl 4] 2-ions and water. Initially, the beaker contains a red-pink solution of cobalt (II) chloride, present as [Co (H 2 O) 6] 2+ ions and chloride ions. Simple carboxylates and halides do not. For example: The reaction is often performed in the presence of charcoal as a catalyst, or hydrogen peroxide is employed in place of air. 6H2O and CoCl2 are weak Lewis acids that convert to many other complexes. Hexahydrate. It contains cobalt in its +2 oxidation state. Find out how LUMITOS supports you with online marketing. [16][17][18], Furthermore, cobalt(II) chloride is suspected of causing cancer (i.e., possibly carcinogenic, IARC Group 2B) as per the International Agency for Research on Cancer (IARC) Monographs. Cobalt chloride can be used to test for chloride ions in this way. Demonstration showing the changing equilibrium of cobalt complexes in solution. It is used to place cobalt into other chemical compounds. Dermatitis. ", "Cobalt crisis turns the eyes of the world onto Australian racing", National Pollutant Inventory – Cobalt fact sheet, IARC Monograph "Cobalt and Cobalt Compounds",, Creative Commons Attribution-ShareAlike License, Cobalt chloride is an established chemical inducer of hypoxia-like responses such as. It can be heated to turn it into the blue form, without water. [20], "CoCl2" redirects here. Names IUPAC name. This 19-electron species is a good reducing agent, being readily oxidised to the yellow 18-electron cobaltacenium cation, which is isoelectronic with ferrocene. This analysis suggests also that the naked cation Co3+ would oxidize chloride to chlorine, precluding the formation of CoCl3. Other highly basic ligands including carbonate, acetylacetonate, and oxalate induce the formation of Co(III) derivatives. To use all the functions on Chemie.DE please activate JavaScript. It is the most common cobalt compound in the lab. Although poisonings have rarely resulted from cobalt compounds, their chronic ingestion has caused serious health problems at doses far less than the lethal dose. 2009 May–Jun;20(3):149-60. International Agency for Research on Cancer, Santa Cruz Biotechnology: Cobalt(II) chloride. The existence of cobalt(III) chloride, CoCl3, is disputed, although it is listed in some compendia. It can be oxidized to cobalt(III) compounds, although cobalt(III) chloride does not exist. Yuzo Saeki, Ryoko Matsuzaki, Naomi Aoyama (1977): "The vapor pressure of cobalt dichloride". [19], In 2005–06, cobalt chloride was the eighth-most-prevalent allergen in patch tests (8.4%). Its chemical formula is CoCl 2. Cobalt chloride is one method used to induce pulmonary arterial hypertension in animals for research and evaluation of treatment efficacy. For the compound COCl, Except where otherwise noted, data are given for materials in their. Cobalt(II) chloride is an inorganic compound of cobalt and chlorine, with the formula CoCl 2. Stated differently, CoCl2 is unreactive toward Cl2. Cobalt(II) chloride is normally found in the red (or pink) form. In the laboratory, cobalt(II) chloride serves as a standard precursor for the synthesis of other cobalt compounds. When it is heated, it turns more blue than when it is cooled. This page was last changed on 9 May 2019, at 07:06. These cobalt (II) complexes are usually either octahedral or tetrahedral. Your browser does not support JavaScript. This page was last edited on 12 October 2020, at 00:48. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE. 6H 2 O is deep rose. In 1966, the addition of cobalt compounds to stabilize beer foam in Canada led to a peculiar form of toxin-induced cardiomyopathy, which came to be known as beer drinker's cardiomyopathy. They are not toxic like lead or mercury compounds, though. John Dallas Donaldson, Detmar Beyersmann, "Cobalt and Cobalt Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. Structure of anhydrous compound. It is a weak oxidizing agent, too weak to ignite things. Because of this dramatic color change and the ease of the hydration/dehydration reaction, "cobalt chloride" is used as an indicator for water. THF in pentane produces the brown, thermally stable cobalt(IV) tetralkyl[13][14] — a rare example of a stable transition metal/saturated alkane compound,[5] different products are obtained in other solvents. Spectrophotometric Analysis of a Cobalt (II) Chloride Solution General Chemistry I (Chemistry 1411) Spectrophotometric Analysis of a Cobalt (II) Chloride Solution Read what you need to know about our industry portal Cobalt(II) chloride Anhydrous. In the presence of ammonia or amines, cobalt(II) is readily oxidised by atmospheric oxygen to give a variety of cobalt(III) complexes.

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